HomeMy WebLinkAboutFile Documents.306 S Garmisch St.0254.2018 (6).ARBKMATERIAL SAFETY DATA SHEET - T03C2011
1 of 7
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME: TAMKO Rolled Roofing that can be Hot Mopped
LABEL: VAPOR-CHAN, TAM CAP
USE & DESCRIPTION: Rolled Asphalt Roofing Products approved for Hot Mopping
CHEMICAL FAMILY: Mixture
MANUFACTURED BY: EMERGENCY TELEPHONE NUMBERS;
TAMKO Building Products, Inc. General Information: 1-417-624-6644 (8 a.m. - 5 p.m. CST)
P. O. Box 1404 Chemtrec: 1-800-424-9300 (24 HOURS)
Joplin, MO 64802-1404
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
USE OF THIS PRODUCT IN “HOT MOPPED” APPLICATIONS MAY EXPOSE WORKERS AND
OTHERS IN THE WORK AREA TO OXIDIZED ASPHALT AND ITS EMISSIONS. THE
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS CLASSIFIED
OCCUPATIONAL EXPOSURES TO OXIDIZED ASPHALT AND ITS EMISSIONS DURING
ROOFING AS A “PROBABLE HUMAN CARCINOGEN.” DURING INSTALLATION AND
REMOVAL OF THIS PRODUCT, INCLUDING “HOT MOPPED” APPLICATION, WORKERS
MUST TAKE PRECAUTIONS TO ASSURE ADEQUATE VENTILATION AND USE EFFECTIVE
PERSONAL PROTECTIVE EQUIPMENT TO PREVENT EXPOSURES TO DUST, FUMES,
VAPORS AND MIST. IT IS THE RESPONSIBILITY OF THE CONTRACTOR AND WORKERS
TO PROTECT THEMSELVES AND OTHERS IN THE WORK AREA FROM EXPOSURE TO
OXIDIZED ASPHALT AND ITS EMISSIONS WHEN APPLYING THIS PRODUCT. THIS
PRODUCT SHOULD NOT BE HEATED OR BURNED USING A DIRECT FLAME DEVICE.
INHALATION OF PRODUCT DUST, FUMES, VAPORS, MIST MAY CAUSE TEMPORARY
UPPER RESPIRATORY IRRITATION.
MAY CAUSE SKIN IRRITATION.
MAY CAUSE EYE IRRITATION.
MAY CAUSE HARMFUL EFFECTS IF SWALLOWED.
UNDER NORMAL CONDITIONS OF USE, THE PRODUCT IS NOT EXPECTED TO CREATE ANY
EMERGENCY HAZARDS.
HMIS Rating:
Health - *1
Flammability - 1
Reactivity - 0
NFPA Rating:
Health - 1
Flammability - 1
Reactivity - 0
POTENTIAL HEALTH EFFECTS:
Eye Contact: If dust enters eye, may cause irritation resulting in tearing, stinging, redness or
swelling.
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
2 of 7
Skin Contact: Repeated contact may cause skin irritation due to roughness of product. Redness,
drying and cracking of the skin (dermatitis) may occur following prolonged and repeated contact.
Prolonged or repeated skin contact could result in absorption of hazardous components.
Ingestion: Ingestion of this product may cause irritation of the digestive tract followed by vomiting.
Avoid aspiration of vomit into the lungs which can cause inflammation or pneumonitis.
Inhalation: Exposure to dust, fumes, vapors, mist may cause irritation of the nose and throat Use
of this product in well-ventilated working conditions is not expected to cause adverse effects.
Chronic Effect/Carcinogenicity/Special/Toxic:
Can cause cancer. Can cause silicosis and other permanent lung damage.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS No. % by Weight
Mineral Granules* NE <45
Limestone* 1317-65-3 <35
Oxidized Asphalt 64742-93-4 <30
Sand* 14808-60-7 <10
Fiberglass Mat NE <4
Fiberglass 65997-17-3 <4
Urea Formaldehyde 9011-05-6 >0.1
Binder
Formaldehyde 50-00-0 <0.1
*Contains Crystalline Silica
Quartz 14808-60-7 >0.1
NE = Not established
4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of cool water for at least 20 minutes,
occasionally lifting the eye lids to ensure thorough rinsing. Get medical attention if irritation persists.
SKIN CONTACT: Clean any exposed skin with warm soapy water if possible. If not, and a
waterless hand cleaner is used, it should be without pumice. Do not use solvents or thinners to
remove material from skin. Get medical attention if irritation persists or develops.
INGESTION: If swallowed, do not induce vomiting. If vomiting occurs, keep head lower than hips
to avoid aspiration of vomit into the lungs which can cause inflammation or pneumonitis. Call poison
control center or get immediate medical attention.
INHALATION: If inhalation of dust, fume, vapor, mist occurs, remove person to fresh air. Drink
water to clear throat or blow nose to clear. If not breathing, give artificial respiration or give oxygen
by trained personnel and get immediate medical attention.
NOTES TO PHYSICIAN: Treatment should be based on removing the source of irritation with
treatment of symptoms as necessary.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Dry chemical, CO², or foam preferred. Avoid use of straight-stream
water.
SPECIAL FIRE FIGHTING PROCEDURES: Combustible. Avoid breathing fumes. Firefighters
should not enter confined spaces without wearing NIOSH approved positive pressure breathing
apparatus (SCBA) with full face mask and full protective equipment.
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
3 of 7
UNUSUAL FIRE OR EXPLOSION HAZARDS: When heated, fumes may burn if ignition source is
provided. Petroleum asphalt fumes can explode if emitted in an enclosed environment and supplied
with an ignition source. Burning product will cause thick black smoke.
SEE SECTION 10 FOR COMBUSTION PRODUCTS
6. ACCIDENTAL RELEASE MEASURES
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED: Pick up large pieces. Do not dry
sweep dusts or blow with air in confined area.
WASTE DISPOSAL METHODS: Dispose in accordance with applicable Federal, State, and Local
regulations. Do not burn.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE: Store away from heat and all ignition sources and open flames in
accordance with applicable laws and regulations. THIS PRODUCT SHOULD NOT BE HEATED
OR BURNED USING A DIRECT FLAME DEVICE.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Follow recommended work
practices and use recommended personal protective clothing and equipment. See Section 8 of
this MSDS.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
9.
Exposure Limits *
Components CAS No. OSHA ACGIH
Raw Products TWA STEL TWA STEL Unit
Oxidized Asphalt 64742-93-4 NE NE 0.5*** NE mg/m3
Limestone 1317-65-3 15/5** NE 10/3** NE mg/m3
Fiberglass 65997-17-3 1/5** NE 5 NE mg/m3
Formaldehyde 50-00-0 0.75 2 NE 0.3 ppm
Crystalline Silica
Quartz 14808-60-7 See 1910.1000 Table Z3 NE 0.025 NE mg/m3
NE= Not established
* Note: Due to the form of the product, hazardous exposures arising from exposure to this product are not expected to
occur. Gloves must be worn when handling and adequate ventilation must be provided during roofing related activities.
** Total Nuisance Dust/Respirable Dust
*** Asphalt Fume
NIOSH GUIDELINES: The National Institute for Occupational Safety and Health (NIOSH) has
published detailed guidelines for roofing contractors and workers applying asphalt roofing
systems using hot liquid asphalt to minimize the asphalt fume exposures of workers and
others near the roofing operation. The guidelines are contained in DHHS (NIOSH)
Publication No. 2003-107, entitled “Reducing Roofers’ Exposure to Asphalt Fumes”. The
publication is available on NIOSH’s website at: http://www.cdc.gov/niosh/docs/2003-
107/pdfs/2003-107.pdf.
RESPIRATORY PROTECTION: Normally not needed in well-ventilated areas. However, if product
is being installed using hot liquid asphalt, NIOSH guidelines recommend use of appropriate
respirator to limit inhalation of fumes. If not using hot liquid asphalt, and applicable exposure
standards are exceeded or can be exceeded, introduce ventilation to remove dust. If increased
ventilation is not possible, use a NIOSH/MSHA approved air-purifying respirator. If concentrations
are sufficiently high that this respirator is inadequate, or high enough to cause oxygen deficiency,
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
4 of 7
use a positive pressure self-contained breathing apparatus (SCBA). Follow all applicable respirator
use, fitting, and training standards and regulations.
VENTILATION: Use only with adequate ventilation to maintain exposures below applicable
exposure limits. Where the product is applied using hot liquid asphalt, follow NIOSH
recommended practices for controlling inhalation exposures to asphalt fumes.
EYE PROTECTION: Chemical safety goggles with side-shields or face shield must be used if eye
contact is possible.
SKIN: Must wear leather or heat-resistant gloves, long-sleeve cotton shirt, long pants with no
cuffs, and non-skid shoes or boots with 6-inch leather uppers during application and/or tear off
activities.
10. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Granular surface on asphalt coated mat.
ODOR THRESHOLD: Not Applicable
pH: Not Applicable
BOILING POINT: >700 ºF
MELTING POINT/ Freezing Point: >200 ºF
INITIAL BOILING POINT AND BOLING RANGE: Not Applicable
FLASH POINT: Not Applicable
EVAPORATION RATE (BUTYL ACETATE = 1): <0.1
FLAMMABILITY (SOLID AND GAS): Not Applicable
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: Not Applicable
VAPOR PRESSURE: Not Applicable
VAPOR DENSITY (AIR = 1): Not Applicable
SPECIFIC GRAVITY/RELATIVE DENSITY: Variable
SOLUBILITY (IES): No data available
PARTITION COEFFICIENT; N-OCTANOL/WATER: Not Applicable
AUTOIGNITION TEMPERATURE: >460ºC/860ºF
DECOMPOSITION TEMPERATURE: Not Applicable
VISCOSITY: Not Applicable
10. STABILITY AND REACTIVITY
STABILITY: Stable
CONDITIONS TO AVOID: Keep from heat, sparks, open flame and other sources of ignition.
Avoid contact with strong oxidizing agents. THIS PRODUCT SHOULD NOT BE HEATED OR
BURNED USING A DIRECT FLAME DEVICE.
HAZARDOUS REACTION: Polymerization will not occur.
INCOMPATIBILTY (MATERIALS TO AVOID): Strong acids or bases, oxidizing agents and
selected amines.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, ozone, hydrogen
sulfide, oxides of sulfur and various hydrocarbons during heating or burning. These combustion
products are not expected unless product is heated or burned.
11. TOXICOLOGICAL INFORMATION
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
5 of 7
EYE – May cause eye irritation.
SKIN – May cause skin irritation.
INHALATION – Dust may cause upper respiratory irritation.
INGESTION – May cause harmful effects if swallowed.
THE FOLLOWING COMPONENT DATA IS PROVIDED FOR USER INFORMATION:
FORMALDEHYDE
Cancer - This product may contain formaldehyde. IARC and NTP have classified formaldehyde as
a human carcinogen based on sufficient evidence that formaldehyde causes nasopharyngeal
cancer in humans, limited evidence for cancer of the nasal cavity and paranasal sinuses, and
"strong but not sufficient evidence" for leukemia. The finding for leukemia reflects the
epidemiologists’ finding of strong evidence in human studies coupled with an inability to identify a
mechanism for induction of leukemia. The physical nature of this product may help limit any
inhalation hazard from formaldehyde during application and in its hardened state.
Acute Effects - The major acute toxic effects caused by formaldehyde exposure via inhalation are
eye, nose, and throat irritation and effects on the nasal cavity. Other effects seen from exposure to
high levels of formaldehyde in humans are coughing, wheezing, chest pains, and bronchitis.
Ingestion exposure to formaldehyde in humans has resulted in corrosion of the gastrointestinal
tract and inflammation and ulceration of the mouth, esophagus, and stomach.
Chronic Effects - In addition to cancer, exposure to formaldehyde by inhalation in humans has
been associated with respiratory symptoms and eye, nose, and throat irritation. Repeated contact
with liquid solutions of formaldehyde has resulted in skin irritation and allergic contact dermatitis in
humans.
SILICA
Cancer - This product contains crystalline silica (quartz). IARC has determined that crystalline
silica inhaled in the form of quartz from occupational sources is carcinogenic to humans (Group 1).
IARC concluded that there was sufficient evidence in humans and animals for the carcinogenicity of
inhaled crystalline silica in the form of quartz from occupational sources. The NTP has classified
silica as known to be a human carcinogen. The physical nature of this product may help limit any
inhalation hazard from crystalline silica during application and in its hardened state. However,
physical forces such as sawing, grinding, drilling and other demolition work on this product may
liberate crystalline silica dust.
Acute Effects - Exposure to silica dust can cause irritation of the eyes, nose and throat. Exposure
to high concentrations can also cause Accelerated Silicosis causing progressive shortness of
breath, fever, coughing, and weight loss.
Chronic Effects – In addition to cancer, breathing of silica over a period of time can cause
damage to the lung tissue or silicosis after long exposure at low concentrations causing shortness
of breath, fever, coughing, and weight loss. Prolonged and repeated exposure to respirable silica-
containing dust may also cause autoimmune disease, kidney disease, tuberculosis, nonmalignant
respiratory disease, and bronchitis.
OXIDIXED ASPHALT
Cancer - This product contains oxidized asphalt. Occupational exposures to oxidized asphalt and
its emissions during roofing activities has been classified by the International Agency for Research
on Cancer (IARC) as “probably carcinogenic to humans” (Group 2A). IARC based this classification
on its finding that available data from studies in humans points to an association between
exposures to oxidized asphalts during roofing and cancers of the lung and upper aerodigestive
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
6 of 7
tract. IARC also determined that there was sufficient evidence of carcinogenicity of extracts and
condensates of oxidized asphalts in experimental animals. The oxidized asphalt in this product may
contain small amounts of Polycyclic Aromatic Hydrocarbons (PAH’s) some of which are recognized
carcinogens in humans or experimental animals. Oxidized asphalt may also cause irritation of the
respiratory tract. The physical nature of this product may help limit any inhalation hazard from the
oxidized asphalt in this product during application and in its hardened state. However, physical
forces such as sawing, grinding, drilling and other demolition work on this product may liberate dust
containing oxidized asphalt. Burning or heating of the product may cause fumes, vapors or mists.
Acute Effects - Inhalation of dust, fumes, vapors, mist may cause nose, throat, and mucous
membrane irritation. Eye contact may cause severe irritation, redness, tearing, and blurred vision.
If ingested, may cause mouth, throat and gastrointestinal tract irritation and upset with possible
nausea, vomiting and diarrhea. See Section 8 for exposure controls.
Chronic Effects - In addition to cancer, prolonged or repeated skin contact may result in dryness
and irritation of the skin. Long term skin exposure to asphalt can increase sensitivity to the sun,
and may cause discoloration. Oxidized asphalt may also cause irritation of the respiratory tract.
12. ECOLOGICAL INFORMATION
Ecotoxicity – No data available
Persistence and degradability – No data available
Bioaccumulative potential – No data available
Mobility in Soil – No data available
Other adverse effects (GHG, Ozone) - No data available
13. DISPOSAL CONSIDERATIONS
This product has not been regulated as a hazardous waste by the USEPA. Dispose in accordance
with Federal, State, and Local regulations.
14. TRANSPORT INFORMATION
This product is not regulated as a hazardous material for transport under 49 CFR or for vessel
transport under the IMDG Code.
UN number: Not applicable
UN Proper Shipping Name: Not applicable
Packing Group, if applicable: Not applicable
Environmental Hazards: Not applicable
Transport in bulk: Not applicable
Special Precautions: Not applicable
5. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT (TSCA): Some components in this product are listed on
the TSCA Inventory.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(CERCLA): None
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), TITLE III:
Section 302 Extremely Hazardous Substances: None
Section 311/312 Hazard Categories: Immediate Health; Delayed Health; Fire Hazard
10/12/18
MSDS Number: T03C2011 – VAPOR CHAN, TAM_CAP Revision Date: December, 2011
7 of 7
Section 313 Reportable Ingredients: This material contains Formaldehyde (CAS# 50-00-
0), which is subject to the reporting requirements of Section 313 of SARA Title III and 40
CFR Part 373.
California Proposition 65:
WARNING: This product contains a chemical known to the State of California to cause cancer and
birth defects or other reproductive harm.
16. OTHER INFORMATION
o Preparation Date: December, 2011 (Replaces previous version of MSDS for product
due to IARC Oxidized Asphalt classification and warning language improvement.)
Disclaimer of Liability
The information and recommendations contained herein are to the best of TAMKO Building Products, Inc.’s
knowledge and belief, accurate and reliable as of the date issued. TAMKO Building Products, Inc. does not warrant
or guarantee their accuracy or reliability, and TAMKO Building Products, Inc. shall not be liable for any loss or
damage arising out of the use thereof.
The information and recommendations are offered for the user’s consideration and examination, and it is the user’s
responsibility to satisfy his or herself that they are suitable and complete for the user’s particular use.
10/12/18