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Home My WebLink AboutFile Documents.504 W Hallam St.0067-2020-BROF (9) Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 1 of 12 Issue date: 2018-08-20 Revision 3.0 Section 1 - PRODUCT AND COMPANY IDENTIFICATION Material Name Carlisle WIP 300HT Synonyms Rubberized asphalt self-adhering sheet with polyethylene film Chemical Family Rubber Asphalt products Product Use waterproofing membrane Restrictions on Use For industrial use only. Manufacturer Information Carlisle Coatings and Waterproofing Incorporated 900 Hensley Lane Wylie, TX 75098 www.carlislewipproducts.com Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. Skin Corrosion/Irritation - Category 2 Reproductive Toxicity - Category 1B Specific Target Organ Toxicity - Single Exposure - Category 2 ( liver, kidneys, thymus ) GHS Label Elements Symbol(s) Signal Word Danger Hazard Statement(s) Causes skin irritation May damage fertility or the unborn child May cause damage to organs Phone Numbers: Medical Emergency CHEMTREC (USA): 800-424-9300 MSDS Assistance; 972-442-6545 Technical Assistance: 888-229-2199 Customer Service: 888-229-0199 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 2 of 12 Issue date: 2018-08-20 Revision 3.0 Precautionary Statement(s) Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/protective clothing/eye protection Wash thoroughly after handling Do not eat, drink or smoke when using this product Response If exposed or concerned: Call a POISON CENTER or doctor/physician IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before use Storage Store locked up Disposal Dispose of contents/container in accordance with local/regional/national/international regulations Other Hazards No additional information available. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Component Name Percent 64742-52-5 Distillates, petroleum, hydrotreated heavy naphthenic 1-5 8052-42-4 Asphalt 0-80 64742-93-4 Asphalt, oxidized 0-80 68955-27-1 Distillates, petroleum, petroleum residues vacuum 0-80 64741-56-6 Residues, petroleum, vacuum 0-80 Mixture Fatty acids, tall-oil, low-boiling 1-5 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 3 of 12 Issue date: 2018-08-20 Revision 3.0 Section 4 - FIRST AID MEASURES Description of Necessary Measures If exposed or concerned: Call a POISON CENTER or doctor/physician. Inhalation Inhalation unlikely due to physical form. Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin Wash exposed skin with soap and water. Take off contaminated clothing and wash before reuse. If skin irritation occurs, get medical advice/attention. Eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Ingestion Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Indication of any immediate medical attention and special treatment needed Treat symptomatically and supportively. Most Important Symptoms/Effects Acute Causes skin irritation. May cause damage to the kidneys, liver, thymus. Delayed May damage fertility or the unborn child. Note to Physicians Contains ASPHALT. Section 5 - FIRE FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Use carbon dioxide, regular dry chemical, regular foam or water. Unsuitable Extinguishing Media None known. Special Hazards Arising from the Chemical Slight fire hazard. Hazardous Combustion Products Oxides of carbon, hydrocarbons 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 4 of 12 Issue date: 2018-08-20 Revision 3.0 Special Protective Equipment and Precautions for Firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Section 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment, see Section 8. Methods and Materials for Containment and Cleaning Up Remove all sources of ignition. Avoid inhalation of material or combustion by-products. Ventilate affected area. Absorb with earth, sand or other non-combustible material and transfer to container. Dispose in accordance with all applicable regulations. Environmental Precautions Avoid release to the environment. Section 7 - HANDLING AND STORAGE Precautions for Safe Handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with eyes, skin and clothing. Wear protective gloves/protective clothing/eye protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. KEEP OUT OF REACH OF CHILDREN. Conditions for Safe Storage, Including any Incompatibilities Store locked up Store in a cool, dry place. Keep container tightly closed and in a well-ventilated place. Keep away from heat and ignition sources. Keep away from incompatible materials. Do not cut, puncture, or weld on or near this container. Incompatible Materials strong acids, strong oxidizing agents Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits Asphalt 8052-42-4 ACGIH: 0.5 mg/m3 TWA as benzene soluble aerosol fume, inhalable fraction NIOSH: 5 mg/m3 Ceiling fume 15 min Mexico: 5 mg/m3 TWA LMPE-PPT 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 5 of 12 Issue date: 2018-08-20 Revision 3.0 10 mg/m3 STEL [LMPE-CT] Biological limit value There are no biological limit values for any of this product's components. Engineering Controls Provide adequate ventilation. Ensure compliance with applicable exposure limits. Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear safety glasses. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin Protection Wear chemical resistant clothing and rubber boots when potential for contact with the material exists. Recommended material: protective skin cream. Respiratory Protection Due to physical form, inhalation is unlikely. Glove Recommendations Wear appropriate chemical resistant gloves. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance Black rubber asphalt with white surface film Physical State solid Odor Slight,petroleum Color Black Odor Threshold Not available pH Not available Melting Point Not available Boiling Point Not available Freezing point Not available Evaporation Rate <0.01 Boiling Point Range Not available Flammability (solid, gas) Not available Autoignition Not available Flash Point >450 °F Lower Explosive Limit Not available Decomposition Not available Upper Explosive Limit Not available Vapor Pressure Not available Vapor Density (air=1) Not available Specific Gravity (water=1) Not available 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 6 of 12 Issue date: 2018-08-20 Revision 3.0 Water Solubility Negligible Partition coefficient: n- octanol/water Not available Viscosity Not available Solubility (Other) Not available Density 1 - 1.2 (relative) Other Information No additional information available. Section 10 - STABILITY AND REACTIVITY Reactivity No reactivity hazard is expected. Chemical Stability Stable under normal conditions of use. Possibility of Hazardous Reactions Hazardous polymerization will not occur. Conditions to Avoid Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. Incompatible Materials strong acids, strong oxidizing agents Hazardous decomposition products Oxides of carbon, hydrocarbons Section 11 - TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation Not a likely route of exposure. Skin Contact Causes skin irritation. Eye Contact May cause mild eye irritation. Ingestion May cause gastrointestinal irritation. Acute and Chronic Toxicity Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 7 of 12 Issue date: 2018-08-20 Revision 3.0 Asphalt (8052-42-4) Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Asphalt, oxidized (64742-93-4) Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Distillates, petroleum, petroleum residues vacuum (68955-27-1) Oral LD50 Rat 4320 mg/kg Dermal LD50 Rabbit >2000 mg/kg Residues, petroleum, vacuum (64741-56-6) Oral LD50 Rat 4320 mg/kg Dermal LD50 Rabbit >2000 mg/kg Fatty acids, tall-oil, low-boiling (Mixture) Oral LD50 Rat >2000 mg/kg Dermal LD50 Rat >2000 mg/kg Immediate Effects Causes skin irritation. May cause damage to the kidneys, liver, thymus. Delayed Effects May damage fertility or the unborn child. Irritation/Corrosivity Data May cause mild skin irritation. May cause mild eye irritation. May cause respiratory irritation. Respiratory Sensitization No data available. Dermal Sensitization No data available. Component Carcinogenicity Asphalt 8052-42-4 ACGIH: A4 - Not Classifiable as a Human Carcinogen (fume, coal tar-free) IARC: Monograph 103 [2013]; Supplement 7 [1987] (extracts of steam-refined and air-refined); Monograph 35 [1985] (Group 2B (possibly carcinogenic to humans)) DFG: Category 2 (considered to be carcinogenic for man, aerosol and vapor) OSHA: Present Asphalt, oxidized 64742-93-4 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 8 of 12 Issue date: 2018-08-20 Revision 3.0 IARC: Monograph 103 [2013] (and their emissions during roofing) (Group 2A (probably carcinogenic to humans)) OSHA: Present Residues, petroleum, vacuum 64741-56-6 IARC: Monograph 103 [2013] (Group 2B (possibly carcinogenic to humans)) OSHA: Present Polycyclic aromatic hydrocarbons 130498-29-2 NTP: Reasonably Anticipated To Be A Human Carcinogen OSHA: Present Germ Cell Mutagenicity No data available. Tumorigenic Data No data available Reproductive Toxicity May damage fertility or the unborn child. Specific Target Organ Toxicity - Single Exposure kidneys, liver, thymus Specific Target Organ Toxicity - Repeated Exposure No target organs identified. Aspiration hazard No data available. Medical Conditions Aggravated by Exposure No data available. Additional Data No additional information available. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Avoid release to the environment. Component Analysis - Aquatic Toxicity Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 9 of 12 Issue date: 2018-08-20 Revision 3.0 Fish: LC50 96 h Oncorhynchus mykiss >5000 mg/L Invertebrate: EC50 48 h Daphnia magna >1000 mg/L IUCLID Asphalt, oxidized 64742-93-4 Algae: EC50 72 h Pseudokirchneriella subcapitata 56 mg/L IUCLID Distillates, petroleum, petroleum residues vacuum 68955-27-1 Fish: LC50 96 h Brachydanio rerio 48 mg/L [semi-static] Residues, petroleum, vacuum 64741-56-6 Fish: LC50 96 h Brachydanio rerio 48 mg/L [semi-static] Fatty acids, tall-oil, low-boiling Mixture Fish: LC50 96 h Brachydanio rerio 50 - 100 mg/L [semi- static] Algae: EC50 72 h Pseudokirchneriella subcapitata >10 mg/L IUCLID Invertebrate: EC50 48 h Daphnia magna 70 mg/L IUCLID Persistence and Degradability No information available for the product. Bioaccumulative Potential No information available for the product. Mobility No information available for the product. Other Toxicity No additional information available. Section 13 - DISPOSAL CONSIDERATIONS Disposal Methods Dispose of contents/container in accordance with local/regional/national/international regulations. Section 14 - TRANSPORT INFORMATION 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 10 of 12 Issue date: 2018-08-20 Revision 3.0 US DOT Information: UN/NA #: Not regulated IATA Information: UN#: Not regulated IMDG Information: UN#: Not regulated TDG Information: UN#: Not regulated Section 15 - REGULATORY INFORMATION U.S. Federal Regulations This material does not contain any chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan. SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactivity: No U.S. State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA Asphalt 8052-42-4 No Yes Yes Yes Yes Asphalt, oxidized 64742-93-4 No No No Yes No Polycyclic aromatic hydrocarbons 130498-29-2 No No Yes Yes Yes Not listed under California Proposition 65 Canadian WHMIS Ingredient Disclosure List (IDL) Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL Component Analysis - Inventory Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 11 of 12 Issue date: 2018-08-20 Revision 3.0 Asphalt (8052-42-4) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Asphalt, oxidized (64742-93-4) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes No Distillates, petroleum, petroleum residues vacuum (68955-27-1) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes No No No Yes No Yes No No Residues, petroleum, vacuum (64741-56-6) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Polycyclic aromatic hydrocarbons (130498-29-2) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX No No No No No No No No No No No Yes Fatty acids, tall-oil, low-boiling (Mixture) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes No No No Yes No Yes Yes No Section 16 - OTHER INFORMATION HMIS Rating Health: 2* Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard 10/26/2020 Safety Data Sheet Material Name: Carlisle WIP 300HT Part No: 305148 309317 ____________________________________________________________ Page 12 of 12 Issue date: 2018-08-20 Revision 3.0 NFPA Ratings Health: 2 Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Summary of Changes Revision Date: 20 August 2018 Revision Note: General Update Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States. Other Information Disclaimer: The information contained herein is based upon data and information available to us, and reflects our best professional judgment. This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used, CCWI Company must rely upon the hazard evaluation of such components submitted by that product’s manufacturer or importer. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information. The results to be obtained from the use thereof, or that any such use does not infringe any patent, since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use. 10/26/2020